cis-Aquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)iodidomanganese(II) iodide monohydrate
نویسنده
چکیده
The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(-) anion and a solvent water mol-ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.092 (7) Å] is 79.9 (1)°. In the crystal, the complex, anion and solvent water mol-ecule are linked by inter-molecular O-H⋯O, O-H⋯I and O-H⋯N hydrogen bonds.
منابع مشابه
cis-Aquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)iodidomanganese(II) iodide dihydrate
The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·2H(2)O, contains a cationic Mn(II) complex, an I(-) anion and two solvent water mol-ecules. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. A...
متن کاملcis-(Acetonitrile-κN)aquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)manganese(II) cis-diaquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)manganese(II) tetrakis(perchlorate) dihydrate
The asymmetric unit of the title compound, [Mn(CH(3)CN)(C(8)H(6)N(4))(2)(H(2)O)][Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(4)·2H(2)O, contains two distinct cationic Mn(II) complexes, four perchlorate anions and two solvent water mol-ecules. In the two complexes, both Mn(II) ions are six-coordinated in a distorted octa-hedral environment, but one Mn ion has a cis-N(5)O coordination geometry defined...
متن کامل(2,2′-Bipyrimidine-κ2 N 1,N 1′)diiodidopalladium(II)
In the title complex, [PdI(2)(C(8)H(6)N(4))], the Pd(II) ion is four-coordinated in a slightly distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis iodide anions. The nearly planar bpym ligand [maximum deviation = 0.053 (3) Å] is slightly inclined to the least-squares plane of the PdI(2)N(2) unit [max...
متن کاملPoly[[(μ-2,2′-bipyrimidine-κ4 N 1,N 1′:N 3,N 3′)(μ-sulfato-κ2 O:O′)zinc(II)] monohydrate]
In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa-hedral environment. The Zn(II) atoms are bridged by both 2,2'-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal-organic solid that contains uncoordinated water mol-ecules in the inter-stitial space. O-H⋯O hydrogen bonding consolidates the crystal structure.
متن کاملcis-Diaquabis(2,2′-bipyrimidine-κ2 N 1,N 1′)manganese(II) bis(perchlorate) nitromethane disolvate monohydrate
The asymmetric unit of the title compound, [Mn(C(8)H(6)N(4))(2)(H(2)O)(2)](ClO(4))(2)·2CH(3)NO(2)·H(2)O, contains one half of a cationic Mn(II) complex, a ClO(4) (-) anion, a nitro-methane solvent mol-ecule and one half-mol-ecule of water. The complex mol-ecule and the solvent water mol-ecule are located on a twofold rotation axis. In the complex, the Mn(II) ion has a distorted cis-N(4)O(2) oct...
متن کامل